Please use this identifier to cite or link to this item: http://hdl.handle.net/11189/5556
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dc.contributor.authorFatoki, Olalekan S-
dc.contributor.authorMzimba, P-
dc.date.accessioned2017-04-12T10:41:28Z-
dc.date.available2017-04-12T10:41:28Z-
dc.date.issued2001-
dc.identifier.issn0379-4350-
dc.identifier.urihttp://hdl.handle.net/11189/5556-
dc.description.abstractIncorporation of wire mesh platinum electrodes into a standard infrared solution cell yielded an inexpensive and easy to maintain optically transparent thin layer electrochemical (OTTLE) cell, well suited for IR analysis of species with half-lives of seconds to minutes. As test bed, two reactions were investigated, which are discussed in the literature: (i) for [Ru3(CO)12] evidence was found for at least partial reversibility in the two-electron reduction process to [Ru3(CO)11]2-, and (ii) for fac-[Re(Cl)(CO)3(4bzpy)2] (4bzpy = 4-benzoylpyridine) additional information concerning the two-step electron reduction of the two benzoylpyridine ligands (again partially reversible) could be obtaineden_US
dc.language.isoenen_US
dc.publisherSouth African Journal of Chemistryen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/za/-
dc.subjectFTIRen_US
dc.subjectOTTLE-
dc.subjectThin layer electrochemical cell-
dc.subjectCarbonyl complexes-
dc.titleFTIR Spectroelectrochemical Studies on [Ru3(CO)12] and fac-[Re(Cl)(CO)3(4bzpy)2] (4bzpy = 4-benzoylpyridine)en_US
dc.type.patentArticleen_US
Appears in Collections:Prof. Olalekan S. Fatoki
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