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http://hdl.handle.net/11189/5556
Title: | FTIR Spectroelectrochemical Studies on [Ru3(CO)12] and fac-[Re(Cl)(CO)3(4bzpy)2] (4bzpy = 4-benzoylpyridine) | Authors: | Fatoki, Olalekan S Mzimba, P |
Keywords: | FTIR;OTTLE;Thin layer electrochemical cell;Carbonyl complexes | Issue Date: | 2001 | Publisher: | South African Journal of Chemistry | Abstract: | Incorporation of wire mesh platinum electrodes into a standard infrared solution cell yielded an inexpensive and easy to maintain optically transparent thin layer electrochemical (OTTLE) cell, well suited for IR analysis of species with half-lives of seconds to minutes. As test bed, two reactions were investigated, which are discussed in the literature: (i) for [Ru3(CO)12] evidence was found for at least partial reversibility in the two-electron reduction process to [Ru3(CO)11]2-, and (ii) for fac-[Re(Cl)(CO)3(4bzpy)2] (4bzpy = 4-benzoylpyridine) additional information concerning the two-step electron reduction of the two benzoylpyridine ligands (again partially reversible) could be obtained | URI: | http://hdl.handle.net/11189/5556 | ISSN: | 0379-4350 |
Appears in Collections: | Prof. Olalekan S. Fatoki |
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FTIR Spectroelectrochemical studies on [Ru3(CO).pdf | 417.65 kB | Adobe PDF | View/Open |
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