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Title: Inclusion Compounds of p-tert-Butylcalixarenes: Structures, Kinetics, and Selectivity
Authors: Ramon, Gaëlle 
Jacobs, Ayesha 
Nassimbeni, Luigi R. 
Yav-Kabwit, Rodriguez 
Keywords: Kinetics;Structures;Selectivity;p-tert-Butylcalixarenes
Issue Date: 2011
Publisher: Crystal Growth and Design
Abstract: Inclusion compounds from p-tert-butylcalix[4] and [6]arenes were grown from chlorobenzene, bromobenzene, benzylamine, and ethylene diamine. The crystal structures of seven new compounds were elucidated, their host guest ratios were established, and their respective thermal stabilities were investigated. The kinetics of desorption of four of the compounds yielded their activation energies of decomposition. We established the selectivity profile of p-tert-butylcalix[4]arene for chlorobenzene versus bromobenzene as guests.
Appears in Collections:Appsc - Journal Articles (DHET subsidised)

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